Browsing Science (Faculty of) by Subject "Water"
Now showing items 1-7 of 7
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1H MAS NMR Study of Water on Pd-MCM-41
(University of Waterloo, 2015-06-18)Hydrogen spillover represents one of the most promising avenues to achieve hydrogen storage at the density required for transportation applications. The spillover phenomenon, however, is a topic of much debate, with many ... -
The Effect of Volatiles (H2O, Cl and CO2) on the Solubility and Partitioning of Platinum and Iridium in Fluid-Melt Systems
(University of Waterloo, 2010-09-01)Volatiles are a fundamental component of the Magmatic-Hydrothermal model of platinum group element (PGE) ore deposition for PGE deposits in layered mafic intrusions such as Bushveld and Stillwater. Volatiles have the ... -
¹H MAS NMR Spectral Coalescence of Water and Hydroxyl Resonances in MCM-41
(University of Waterloo, 2011-09-01)Solid state ¹H MAS NMR spectroscopy was used to investigate the temperature and hydration dependance of water and hydroxyl proton spectra of hydrated mesoporous MCM-41. The NMR spectra show a complex peak structure, with ... -
In Vitro Selection of Chromium-Dependent DNAzymes for Sensing Chromium(III) and Chromium(VI)
(Wiley, 2016-07-04)Chromium is a very important analyte for environmental monitoring, and developing biosensors for chromium is a long-standing analytical challenge. In this work, in vitro selection of RNA-cleaving DNAzymes was carried out ... -
Insights into the Effect of the PDMS-Layer on the Kinetics and Thermodynamics of Analyte Sorption onto the Matrix-Compatible Solid Phase Microextraction Coating
(American Chemical Society, 2017-03-07)The currently presented research investigated the performance of matrix compatible PDMS-overcoated fibers (PDMS-DVB/PDMS) as compared to unmodified PDMS/ DVB coatings using aqueous samples and employing a wide range of ... -
Numerical Simulation and Experimental Validation of Calibrant-Loaded Extraction Phase Standardization Approach
(American Chemical Society, 2016-09-06)We present the kinetics of calibrant release and analyte uptake between the sample and calibrant-loaded extraction phase, CL-EP, with a finite-element analysis (FEA) using COMSOL Multiphysics software package. Effect of ... -
Solid Phase Microextraction On-Fiber Derivatization Using a Stable, Portable, and Reusable Pentafluorophenyl Hydrazine Standard Gas Generating Vial
(American Chemical Society, 2017-07-05)Solid phase microextraction (SPME) on-fiber derivatization methods have facilitated the achievement of lower detection limits and targeted analysis of various substances that exhibit poor chromatographic behavior, thermal ...